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Cell-like model chemical systems are powerful tools that can be used to explore the role of intercellular coupling on population level behaviors in communities of biological cells. We present a new method for fabricating such micro-reactors using the photosensitive Belousov–Zhabotinsky (BZ) reaction system employed in silica microparticles. These BZ micro-reactors have a tunable response to photochemical coupling, varying from a fully excitatory response to a fully inhibitory response. Their response can be tuned through variations in either the reactive mixture or, on an individual micro-reactor level, by changes in parameters used during the fabrication of the silica microparticles. A reaction–diffusion model is used to explore the physicochemical properties of the microparticles that lead to their tunable behavior. 

Cardiac arrythmias are a form of heart disease that contributes toward making heart disease a significant cause of death globally. Irregular rhythms associated with cardiac arrythmias are thought to arise due to singularities in the heart tissue that generate reentrant waves in the underlying excitable medium. A normal approach to removing such singularities is to apply a high voltage electric shock, which effectively resets the phase of the cardiac cells. A concern with the use of this defibrillation technique is that the high-energy shock can cause lasting damage to the heart tissue. Various theoretical works have investigated lower-energy alternatives to defibrillation. In this work, we demonstrate the effectiveness of a low-energy defibrillation method in an experimental 2D Belousov–Zhabotinsky (BZ) system. When implemented as a 2D spatial reaction, the BZ reaction serves as an effective analog of general excitable media and supports regular and reentrant wave activity. The defibrillation technique employed involves targeted low-energy perturbations that can be used to “teleport” and/or annihilate singularities present in the excitable BZ medium. 

Propagating precipitation waves are a remarkable form of spatiotemporal behavior that arise through the coupling of reaction, diffusion, and precipitation. We study a system with a sodium hydroxide outer electrolyte and an aluminum hydroxide inner electrolyte. In a redissolution Liesegang system, a single propagating precipitation band moves down through the gel, with precipitate formed at the band front and precipitate dissolved at the band back. Complex spatiotemporal waves occur within the propagating precipitation band, including counter-rotating spiral waves, target patterns, and annihilation of waves on collision. We have also carried out experiments in thin slices of gel, which have revealed propagating waves of a diagonal precipitation feature within the primary precipitation band. These waves display a wave merging phenomenon in which two horizontally propagating waves merge into a single wave. Computational modeling permits the development of a detailed understanding of the complex dynamical behavior.